Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S⋯O interactions
نویسندگان
چکیده
منابع مشابه
Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: Role of intramolecular non-bonded S⋅⋅⋅O interactions
A new synthetic approach to 2,3-dihydro-4H-1,3-thiazine derivatives based upon reductive rearrangement of 1,2-dithiole-3-ylidene thiones has been developed. In turn, the 1,2-dithiole derivatives were prepared by an efficient, ring-opening-closing process of 2-alkylidene-4-oxothiazolidines, induced in the presence of Lawesson’s reagent by intramolecular non-bonded 1,5-type S⋅⋅⋅O interactions in ...
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ژورنال
عنوان ژورنال: Tetrahedron
سال: 2007
ISSN: 0040-4020
DOI: 10.1016/j.tet.2006.12.075